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Paints Part 2: Failure Mechanisms

CorroZone Podcast · 16 Jun 2026

Paints Part 2: Failure Mechanisms

  • Free
  • Lecture
  • Beginner
  • ~39 min

How coatings fail: water and ion transport through the film to the substrate, anodic undermining versus cathodic disbondment, osmotic and corrosion-driven blistering and how to tell them apart, the mechanical failure modes, UV degradation and chalking, surface-prep defects as initiation sites, and the inspection and maintenance programme.

Show notes

What you'll learn

  • Describe the mechanisms by which water and ions transport through organic coating films and explain the consequences of their arrival at the metal substrate
  • Distinguish between anodic undermining and cathodic disbondment as delamination mechanisms, including the role of cathodic protection in disbondment
  • Explain osmotic and corrosion-driven blistering mechanisms and identify diagnostic indicators that differentiate them
  • Identify the main mechanical failure modes of coatings (cracking, impact, abrasion, erosion) and the conditions that promote each
  • Explain UV degradation of organic coatings, including chalking, gloss loss, and embrittlement, and state why aromatic binders are UV-sensitive
  • Analyse how surface preparation defects act as failure initiation sites for multiple failure mechanisms
  • Describe the main components of a coating inspection and maintenance programme, including visual grading, DFT, holiday detection, and adhesion testing

Who this is for

Anyone beginning their study of corrosion — students, engineers, and technical staff who want a solid foundation in why metals corrode and what can be done about it. No prior background assumed.

What you'll learn

  • Describe the mechanisms by which water and ions transport through organic coating films and explain the consequences of their arrival at the metal substrate
  • Distinguish between anodic undermining and cathodic disbondment as delamination mechanisms, including the role of cathodic protection in disbondment
  • Explain osmotic and corrosion-driven blistering mechanisms and identify diagnostic indicators that differentiate them
  • Identify the main mechanical failure modes of coatings (cracking, impact, abrasion, erosion) and the conditions that promote each
  • Explain UV degradation of organic coatings, including chalking, gloss loss, and embrittlement, and state why aromatic binders are UV-sensitive
  • Analyse how surface preparation defects act as failure initiation sites for multiple failure mechanisms
  • Describe the main components of a coating inspection and maintenance programme, including visual grading, DFT, holiday detection, and adhesion testing

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