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Galvanic Corrosion

CorroZone Podcast · 16 Jun 2026

Galvanic Corrosion

  • Free
  • Lecture
  • Beginner
  • ~34 min

Dissimilar-metal corrosion: the potential-difference, electron-flow and ionic-current mechanism, the galvanic series versus the standard electrochemical series, picking anode and cathode, the decisive cathode-to-anode area ratio, the environmental factors, Evans-diagram analysis of a couple, and the full set of mitigation strategies.

Show notes

What you'll learn

  • Explain the electrochemical mechanism of galvanic corrosion including the roles of potential difference, electron flow, and ionic current
  • Distinguish the galvanic series from the standard electrochemical series and explain why the two can differ substantially for real alloys
  • Identify which metal in a galvanic couple will act as the anode and which as the cathode using the galvanic series
  • Explain the critical importance of the cathode-to-anode area ratio and predict whether a given configuration is dangerous or acceptable
  • Describe how electrolyte conductivity, distance, pH, temperature, and dissolved oxygen affect galvanic corrosion severity
  • Use an Evans diagram to determine the galvanic potential and corrosion current for a dissimilar-metal couple
  • Predict qualitatively how changes in cathode area, oxygen concentration, or inhibitor addition shift Evans diagram intersections
  • Apply mitigation strategies including materials selection, electrical insulation, cathode coating, cathodic protection, and design optimisation
  • Identify appropriate mitigation approaches for galvanic corrosion in marine, aerospace, pipeline, and plumbing contexts

Who this is for

Anyone beginning their study of corrosion — students, engineers, and technical staff who want a solid foundation in why metals corrode and what can be done about it. No prior background assumed.

What you'll learn

  • Explain the electrochemical mechanism of galvanic corrosion including the roles of potential difference, electron flow, and ionic current
  • Distinguish the galvanic series from the standard electrochemical series and explain why the two can differ substantially for real alloys
  • Identify which metal in a galvanic couple will act as the anode and which as the cathode using the galvanic series
  • Explain the critical importance of the cathode-to-anode area ratio and predict whether a given configuration is dangerous or acceptable
  • Describe how electrolyte conductivity, distance, pH, temperature, and dissolved oxygen affect galvanic corrosion severity
  • Use an Evans diagram to determine the galvanic potential and corrosion current for a dissimilar-metal couple
  • Predict qualitatively how changes in cathode area, oxygen concentration, or inhibitor addition shift Evans diagram intersections
  • Apply mitigation strategies including materials selection, electrical insulation, cathode coating, cathodic protection, and design optimisation
  • Identify appropriate mitigation approaches for galvanic corrosion in marine, aerospace, pipeline, and plumbing contexts

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