
CorroZone Podcast · 16 Jun 2026
Galvanic Corrosion
- Free
- Lecture
- Beginner
- ~34 min
Dissimilar-metal corrosion: the potential-difference, electron-flow and ionic-current mechanism, the galvanic series versus the standard electrochemical series, picking anode and cathode, the decisive cathode-to-anode area ratio, the environmental factors, Evans-diagram analysis of a couple, and the full set of mitigation strategies.
Show notes
What you'll learn
- Explain the electrochemical mechanism of galvanic corrosion including the roles of potential difference, electron flow, and ionic current
- Distinguish the galvanic series from the standard electrochemical series and explain why the two can differ substantially for real alloys
- Identify which metal in a galvanic couple will act as the anode and which as the cathode using the galvanic series
- Explain the critical importance of the cathode-to-anode area ratio and predict whether a given configuration is dangerous or acceptable
- Describe how electrolyte conductivity, distance, pH, temperature, and dissolved oxygen affect galvanic corrosion severity
- Use an Evans diagram to determine the galvanic potential and corrosion current for a dissimilar-metal couple
- Predict qualitatively how changes in cathode area, oxygen concentration, or inhibitor addition shift Evans diagram intersections
- Apply mitigation strategies including materials selection, electrical insulation, cathode coating, cathodic protection, and design optimisation
- Identify appropriate mitigation approaches for galvanic corrosion in marine, aerospace, pipeline, and plumbing contexts
Who this is for
Anyone beginning their study of corrosion — students, engineers, and technical staff who want a solid foundation in why metals corrode and what can be done about it. No prior background assumed.
What you'll learn
- Explain the electrochemical mechanism of galvanic corrosion including the roles of potential difference, electron flow, and ionic current
- Distinguish the galvanic series from the standard electrochemical series and explain why the two can differ substantially for real alloys
- Identify which metal in a galvanic couple will act as the anode and which as the cathode using the galvanic series
- Explain the critical importance of the cathode-to-anode area ratio and predict whether a given configuration is dangerous or acceptable
- Describe how electrolyte conductivity, distance, pH, temperature, and dissolved oxygen affect galvanic corrosion severity
- Use an Evans diagram to determine the galvanic potential and corrosion current for a dissimilar-metal couple
- Predict qualitatively how changes in cathode area, oxygen concentration, or inhibitor addition shift Evans diagram intersections
- Apply mitigation strategies including materials selection, electrical insulation, cathode coating, cathodic protection, and design optimisation
- Identify appropriate mitigation approaches for galvanic corrosion in marine, aerospace, pipeline, and plumbing contexts